<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Zheng, Yifan</style></author><author><style face="normal" font="default" size="100%">Goh, Tenghooi</style></author><author><style face="normal" font="default" size="100%">Fan, Pu</style></author><author><style face="normal" font="default" size="100%">Shi, Wei</style></author><author><style face="normal" font="default" size="100%">Yu, Junsheng</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">6. Toward Efficient Thick Active PTB7 Photovoltaic Layers Using Diphenyl Ether as a Solvent Additive</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Applied Materials &amp; Interfaces</style></secondary-title><short-title><style face="normal" font="default" size="100%">ACS Appl. Mater. Interfaces</style></short-title></titles><dates><year><style  face="normal" font="default" size="100%">2016</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Oct-06-2017</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">http://pubs.acs.org/doi/abs/10.1021/acsami.6b03453</style></url></web-urls></urls><volume><style face="normal" font="default" size="100%">8</style></volume><pages><style face="normal" font="default" size="100%">15724 - 15731</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><issue><style face="normal" font="default" size="100%">24</style></issue></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Lee, Jongho</style></author><author><style face="normal" font="default" size="100%">Boo, Chanhee</style></author><author><style face="normal" font="default" size="100%">Ryu, Won-Hee</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author><author><style face="normal" font="default" size="100%">Elimelech, Menachem</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">7. Development of Omniphobic Desalination Membranes Using a Charged Electrospun Nanofiber Scaffold</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Applied Materials &amp; Interfaces</style></secondary-title><short-title><style face="normal" font="default" size="100%">ACS Appl. Mater. Interfaces</style></short-title></titles><dates><year><style  face="normal" font="default" size="100%">2016</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Apr-05-2016</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">http://pubs.acs.org/doi/abs/10.1021/acsami.6b02419</style></url></web-urls></urls><volume><style face="normal" font="default" size="100%">8</style></volume><pages><style face="normal" font="default" size="100%">11154 - 11161</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><issue><style face="normal" font="default" size="100%">17</style></issue></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Gittleson, Forrest S.</style></author><author><style face="normal" font="default" size="100%">Ryu, Won-Hee</style></author><author><style face="normal" font="default" size="100%">Schwab, Mark</style></author><author><style face="normal" font="default" size="100%">Tong, Xiao</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">8. Pt and Pd catalyzed oxidation of Li &lt;sub&gt;2&lt;/sub&gt;               O &lt;sub&gt;2&lt;/sub&gt;               and DMSO during Li–O               &lt;sub&gt;2&lt;/sub&gt;               battery charging</style></title><secondary-title><style face="normal" font="default" size="100%">Chem. Commun.</style></secondary-title><short-title><style face="normal" font="default" size="100%">Chem. Commun.</style></short-title></titles><dates><year><style  face="normal" font="default" size="100%">2016</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Jan-01-2016</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">http://xlink.rsc.org/?DOI=C6CC01778A</style></url></web-urls></urls><volume><style face="normal" font="default" size="100%">52</style></volume><pages><style face="normal" font="default" size="100%">6605 - 6608</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><issue><style face="normal" font="default" size="100%">39</style></issue></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Ryu, Won-Hee</style></author><author><style face="normal" font="default" size="100%">Wilson, Hope</style></author><author><style face="normal" font="default" size="100%">Sohn, Sungwoo</style></author><author><style face="normal" font="default" size="100%">Li, Jinyang</style></author><author><style face="normal" font="default" size="100%">Tong, Xiao</style></author><author><style face="normal" font="default" size="100%">Shaulsky, Evyatar</style></author><author><style face="normal" font="default" size="100%">Schroers, Jan</style></author><author><style face="normal" font="default" size="100%">Elimelech, Menachem</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">B1. Heterogeneous WS &lt;sub&gt; &lt;i&gt;x&lt;/i&gt; &lt;/sub&gt;               /WO &lt;sub&gt;3&lt;/sub&gt;               Thorn-Bush Nanofiber Electrodes for Sodium-Ion Batteries</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Nano</style></secondary-title><short-title><style face="normal" font="default" size="100%">ACS Nano</style></short-title></titles><dates><year><style  face="normal" font="default" size="100%">2016</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Mar-02-2017</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">http://pubs.acs.org/doi/abs/10.1021/acsnano.5b06538</style></url></web-urls></urls><language><style face="normal" font="default" size="100%">eng</style></language></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Ryu, W. H.</style></author><author><style face="normal" font="default" size="100%">Gittleson, F. S.</style></author><author><style face="normal" font="default" size="100%">Schwab, M.</style></author><author><style face="normal" font="default" size="100%">Goh, T.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">A mesoporous catalytic membrane architecture for lithium-oxygen battery systems</style></title><secondary-title><style face="normal" font="default" size="100%">Nano LettNano Lett</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">catalyst</style></keyword><keyword><style  face="normal" font="default" size="100%">electrospinning</style></keyword><keyword><style  face="normal" font="default" size="100%">Lithium-oxygen batteries</style></keyword><keyword><style  face="normal" font="default" size="100%">mesoporous polymer membrane</style></keyword><keyword><style  face="normal" font="default" size="100%">oxygen evolution reaction</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2015</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Jan 14</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">1</style></number><volume><style face="normal" font="default" size="100%">15</style></volume><pages><style face="normal" font="default" size="100%">434-41</style></pages><isbn><style face="normal" font="default" size="100%">1530-6992 (Electronic)&lt;br/&gt;1530-6984 (Linking)</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Controlling the mesoscale geometric configuration of catalysts on the oxygen electrode is an effective strategy to achieve high reversibility and efficiency in Li-O2 batteries. Here we introduce a new Li-O2 cell architecture that employs a catalytic polymer-based membrane between the oxygen electrode and the separator. The catalytic membrane was prepared by immobilization of Pd nanoparticles on a polyacrylonitrile (PAN) nanofiber membrane and is adjacent to a carbon nanotube electrode loaded with Ru nanoparticles. During oxide product formation, the insulating PAN polymer scaffold restricts direct electron transfer to the Pd catalyst particles and prevents the direct blockage of Pd catalytic sites. The modified Li-O2 battery with a catalytic membrane showed a stable cyclability for 60 cycles with a capacity of 1000 mAh/g and a reduced degree of polarization ( approximately 0.3 V) compared to cells without a catalytic membrane. We demonstrate the effects of a catalytic membrane on the reaction characteristics associated with morphological and structural features of the discharge products via detailed ex situ characterization.&lt;/p&gt;
</style></abstract><accession-num><style face="normal" font="default" size="100%">25546408</style></accession-num><notes><style face="normal" font="default" size="100%">Ryu, Won-Hee&lt;br/&gt;Gittleson, Forrest S&lt;br/&gt;Schwab, Mark&lt;br/&gt;Goh, Tenghooi&lt;br/&gt;Taylor, Andre D&lt;br/&gt;eng&lt;br/&gt;Research Support, Non-U.S. Gov't&lt;br/&gt;Research Support, U.S. Gov't, Non-P.H.S.&lt;br/&gt;2014/12/30 06:00&lt;br/&gt;Nano Lett. 2015 Jan 14;15(1):434-41. doi: 10.1021/nl503760n. Epub 2014 Dec 30.</style></notes><auth-address><style face="normal" font="default" size="100%">Department of Chemical and Environmental Engineering, Yale University , 9 Hillhouse Avenue, New Haven, Connecticut 06520, United States.</style></auth-address></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Singer, J. P.</style></author><author><style face="normal" font="default" size="100%">Gopinadhan, M.</style></author><author><style face="normal" font="default" size="100%">Shao, Z.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author><author><style face="normal" font="default" size="100%">Schroers, J.</style></author><author><style face="normal" font="default" size="100%">Osuji, C. O.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Nanoimprinting sub-100 nm features in a photovoltaic nanocomposite using durable bulk metallic glass molds</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Appl Mater InterfacesACS Appl Mater Interfaces</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">bulk heterojunctions</style></keyword><keyword><style  face="normal" font="default" size="100%">bulk metallic glass</style></keyword><keyword><style  face="normal" font="default" size="100%">nanoimprint lithography</style></keyword><keyword><style  face="normal" font="default" size="100%">organic photovoltaics</style></keyword><keyword><style  face="normal" font="default" size="100%">polymer patterning</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2015</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Feb 18</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">6</style></number><volume><style face="normal" font="default" size="100%">7</style></volume><pages><style face="normal" font="default" size="100%">3456-61</style></pages><isbn><style face="normal" font="default" size="100%">1944-8252 (Electronic)&lt;br/&gt;1944-8244 (Linking)</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The use of bulk metallic glass (BMG) for the nanoimprint of high-aspect-ratio (&amp;gt;3) features into functional polymers is investigated. To accomplish this, the most critical aspect is the successful demolding of the imprinted polymer. By fluorosilane functionalization of the BMG surface and optimization of processing temperature, high aspect pore features down to 45 nm diameters are introduced into the surface of two organic photovoltaic systems: poly(3-hexylthiophene-2,5-diyl) (P3HT) and 1:1 mixtures of P3HT with Phenyl-C61-butyric acid methyl ester (PCBM). The crystallinity of P3HT demands higher forming temperatures and pressures that are difficult to obtain with conventional soft nanoimprint lithography molds. The ability to accommodate a wide range of processing conditions and the low cost of fabricating molds with nanometer-scale features point to the large potential of nanotextured BMGs as an economical and scalable imprint material for high-resolution applications.&lt;/p&gt;
</style></abstract><accession-num><style face="normal" font="default" size="100%">25639309</style></accession-num><notes><style face="normal" font="default" size="100%">Singer, Jonathan P&lt;br/&gt;Gopinadhan, Manesh&lt;br/&gt;Shao, Zhen&lt;br/&gt;Taylor, Andre D&lt;br/&gt;Schroers, Jan&lt;br/&gt;Osuji, Chinedum O&lt;br/&gt;eng&lt;br/&gt;Letter&lt;br/&gt;Research Support, Non-U.S. Gov't&lt;br/&gt;Research Support, U.S. Gov't, Non-P.H.S.&lt;br/&gt;2015/02/03 06:00&lt;br/&gt;ACS Appl Mater Interfaces. 2015 Feb 18;7(6):3456-61. doi: 10.1021/am507368g. Epub 2015 Feb 5.</style></notes><auth-address><style face="normal" font="default" size="100%">Department of Chemical and Environmental Engineering and section signDepartment of Mechanical Engineering and Materials Science, Yale University , New Haven, Connecticut 06511, United States.</style></auth-address></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Gittleson, Forrest S.</style></author><author><style face="normal" font="default" size="100%">Yao, Koffi P. C.</style></author><author><style face="normal" font="default" size="100%">Kwabi, David G.</style></author><author><style face="normal" font="default" size="100%">Sayed, Sayed Youssef</style></author><author><style face="normal" font="default" size="100%">Ryu, Won-Hee</style></author><author><style face="normal" font="default" size="100%">Shao-Horn, Yang</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Raman Spectroscopy in Lithium-Oxygen Battery Systems</style></title><secondary-title><style face="normal" font="default" size="100%">ChemElectroChem</style></secondary-title><short-title><style face="normal" font="default" size="100%">ChemElectroChem</style></short-title></titles><dates><year><style  face="normal" font="default" size="100%">2015</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Jan-10-2015</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">http://doi.wiley.com/10.1002/celc.v2.10http://doi.wiley.com/10.1002/celc.201500218http://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fcelc.201500218</style></url></web-urls></urls><volume><style face="normal" font="default" size="100%">2</style></volume><pages><style face="normal" font="default" size="100%">1446 - 1457</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><issue><style face="normal" font="default" size="100%">10</style></issue></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Gittleson, Forrest S.</style></author><author><style face="normal" font="default" size="100%">Hwang, Daniel</style></author><author><style face="normal" font="default" size="100%">Ryu, Won-Hee</style></author><author><style face="normal" font="default" size="100%">Hashmi, Sara M.</style></author><author><style face="normal" font="default" size="100%">Hwang, Jonathan</style></author><author><style face="normal" font="default" size="100%">Goh, Tenghooi</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Ultrathin Nanotube/Nanowire Electrodes by Spin–Spray Layer-by-Layer Assembly: A Concept for Transparent Energy Storage</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Nano</style></secondary-title><short-title><style face="normal" font="default" size="100%">ACS Nano</style></short-title></titles><dates><year><style  face="normal" font="default" size="100%">2015</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Mar-10-2017</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">http://pubs.acs.org/doi/10.1021/acsnano.5b03578http://pubs.acs.org/doi/pdf/10.1021/acsnano.5b03578</style></url></web-urls></urls><volume><style face="normal" font="default" size="100%">9</style></volume><pages><style face="normal" font="default" size="100%">10005 - 10017</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><issue><style face="normal" font="default" size="100%">10</style></issue></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Gittleson, F. S.</style></author><author><style face="normal" font="default" size="100%">Sekol, R. C.</style></author><author><style face="normal" font="default" size="100%">Doubek, G.</style></author><author><style face="normal" font="default" size="100%">Linardi, M.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Catalyst and electrolyte synergy in Li-O2 batteries</style></title><secondary-title><style face="normal" font="default" size="100%">Phys Chem Chem PhysPhys Chem Chem Phys</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Feb 21</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">7</style></number><volume><style face="normal" font="default" size="100%">16</style></volume><pages><style face="normal" font="default" size="100%">3230-7</style></pages><isbn><style face="normal" font="default" size="100%">1463-9084 (Electronic)&lt;br/&gt;1463-9076 (Linking)</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Understanding the interactions between catalyst and electrolyte in Li-O2 systems is crucial to improving capacities, efficiencies, and cycle life. In this study, supported noble metal catalysts Pt/C, Pd/C, and Au/C were paired with popular Li-O2 electrolyte solvents dimethoxyethane (DME), tetraglyme (TEGDME), and dimethyl sulfoxide (DMSO). The effects of these combinations on stability, kinetics, and activity were assessed. We show evidence of a synergistic effect between Pt and Pd catalysts and a DMSO-based electrolyte which enhances the kinetics of oxygen reduction and evolution reactions. DME and TEGDME are more prone to decomposition and less kinetically favorable for oxygen reduction and evolution than DMSO. While the order of oxygen reduction onset potentials with each catalyst was found to be consistent across electrolyte (Pd &amp;gt; Pt &amp;gt; Au), larger overpotentials with DME and TEGDME, and negative shifts in onset after only five cycles favor the stability of a DMSO electrolyte. Full cell cycling experiments confirm that catalyst-DMSO combinations produce up to 9 times higher discharge capacities than the same with TEGDME after 20 cycles ( approximately 707.4 vs. 78.8 mA h g(-1) with Pd/C). Ex situ EDS and in situ EIS analyses of resistive species in the cathode suggest that improvements in capacity with DMSO are due to a combination of greater electrolyte conductivity and catalyst synergies. Our findings demonstrate that co-selection of catalyst and electrolyte is necessary to exploit chemical synergies and improve the performance of Li-O2 cells.&lt;/p&gt;
</style></abstract><accession-num><style face="normal" font="default" size="100%">24406938</style></accession-num><notes><style face="normal" font="default" size="100%">Gittleson, Forrest S&lt;br/&gt;Sekol, Ryan C&lt;br/&gt;Doubek, Gustavo&lt;br/&gt;Linardi, Marcelo&lt;br/&gt;Taylor, Andre D&lt;br/&gt;eng&lt;br/&gt;England&lt;br/&gt;2014/01/11 06:00&lt;br/&gt;Phys Chem Chem Phys. 2014 Feb 21;16(7):3230-7. doi: 10.1039/c3cp54555e. Epub 2014 Jan 10.</style></notes><auth-address><style face="normal" font="default" size="100%">Department of Chemical and Environmental Engineering, Yale University, 9 Hillhouse Ave, New Haven, CT, USA. andre.taylor@yale.edu.</style></auth-address></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Li, X.</style></author><author><style face="normal" font="default" size="100%">Guard, L. M.</style></author><author><style face="normal" font="default" size="100%">Jiang, J.</style></author><author><style face="normal" font="default" size="100%">Sakimoto, K.</style></author><author><style face="normal" font="default" size="100%">Huang, J. S.</style></author><author><style face="normal" font="default" size="100%">Wu, J.</style></author><author><style face="normal" font="default" size="100%">Li, J.</style></author><author><style face="normal" font="default" size="100%">Yu, L.</style></author><author><style face="normal" font="default" size="100%">Pokhrel, R.</style></author><author><style face="normal" font="default" size="100%">Brudvig, G. W.</style></author><author><style face="normal" font="default" size="100%">Ismail-Beigi, S.</style></author><author><style face="normal" font="default" size="100%">Hazari, N.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Controlled doping of carbon nanotubes with metallocenes for application in hybrid carbon nanotube/Si solar cells</style></title><secondary-title><style face="normal" font="default" size="100%">Nano LettNano Lett</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Jun 11</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">6</style></number><volume><style face="normal" font="default" size="100%">14</style></volume><pages><style face="normal" font="default" size="100%">3388-94</style></pages><isbn><style face="normal" font="default" size="100%">1530-6992 (Electronic)&lt;br/&gt;1530-6984 (Linking)</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;There is considerable interest in the controlled p-type and n-type doping of carbon nanotubes (CNT) for use in a range of important electronics applications, including the development of hybrid CNT/silicon (Si) photovoltaic devices. Here, we demonstrate that easy to handle metallocenes and related complexes can be used to both p-type and n-type dope single-walled carbon nanotube (SWNT) thin films, using a simple spin coating process. We report n-SWNT/p-Si photovoltaic devices that are &amp;gt;450 times more efficient than the best solar cells of this type currently reported and show that the performance of both our n-SWNT/p-Si and p-SWNT/n-Si devices is related to the doping level of the SWNT. Furthermore, we establish that the electronic structure of the metallocene or related molecule can be correlated to the doping level of the SWNT, which may provide the foundation for controlled doping of SWNT thin films in the future.&lt;/p&gt;
</style></abstract><accession-num><style face="normal" font="default" size="100%">24779408</style></accession-num><notes><style face="normal" font="default" size="100%">Li, Xiaokai&lt;br/&gt;Guard, Louise M&lt;br/&gt;Jiang, Jie&lt;br/&gt;Sakimoto, Kelsey&lt;br/&gt;Huang, Jing-Shun&lt;br/&gt;Wu, Jianguo&lt;br/&gt;Li, Jinyang&lt;br/&gt;Yu, Lianqing&lt;br/&gt;Pokhrel, Ravi&lt;br/&gt;Brudvig, Gary W&lt;br/&gt;Ismail-Beigi, Sohrab&lt;br/&gt;Hazari, Nilay&lt;br/&gt;Taylor, Andre D&lt;br/&gt;eng&lt;br/&gt;Research Support, Non-U.S. Gov't&lt;br/&gt;Research Support, U.S. Gov't, Non-P.H.S.&lt;br/&gt;2014/05/02 06:00&lt;br/&gt;Nano Lett. 2014 Jun 11;14(6):3388-94. doi: 10.1021/nl500894h. Epub 2014 May 13.</style></notes><auth-address><style face="normal" font="default" size="100%">Department of Chemical and Environmental Engineering and double daggerDepartment of Chemistry, Yale University , New Haven, Connecticut 06511, United States.</style></auth-address></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Gittleson, F. S.</style></author><author><style face="normal" font="default" size="100%">Ryu, W. H.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Operando observation of the gold-electrolyte interface in Li-O2 batteries</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Appl Mater InterfacesACS Appl Mater Interfaces</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">electrochemical impedance spectroscopy</style></keyword><keyword><style  face="normal" font="default" size="100%">Li2O2</style></keyword><keyword><style  face="normal" font="default" size="100%">LiO2</style></keyword><keyword><style  face="normal" font="default" size="100%">lithium-air</style></keyword><keyword><style  face="normal" font="default" size="100%">lithium-oxygen</style></keyword><keyword><style  face="normal" font="default" size="100%">Raman spectroscopy</style></keyword><keyword><style  face="normal" font="default" size="100%">Sers</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Nov 12</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">21</style></number><volume><style face="normal" font="default" size="100%">6</style></volume><pages><style face="normal" font="default" size="100%">19017-25</style></pages><isbn><style face="normal" font="default" size="100%">1944-8252 (Electronic)&lt;br/&gt;1944-8244 (Linking)</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Observing the cathode interface in Li-O2 batteries during cycling is necessary to improve our understanding of discharge product formation and evolution in practical cells. In this work a gold electrode surface is monitored by operando surface-enhanced Raman spectroscopy during typical discharge and charge cycling. During discharge, we observe the precipitation of stable and reversible lithium superoxide (LiO2), in contrast to reports that suggest it is a mere intermediate in the formation of lithium peroxide (Li(2)O2). Some LiO2 is further reduced to Li(2)O2 producing a coating of insulating discharge products that renders the gold electrode inactive. Upon charging, a superficial layer of these species ( approximately 1 nm) are preferentially oxidized at low overpotentials (&amp;lt;0.6 V), leaving residual products in poor contact with the electrode surface. In situ electrochemical impedance spectroscopy is also used to distinguish between LiO2 and Li(2)O2 products using frequency-dependent responses and to correlate their reduction and oxidation potentials to the accepted mechanism of Li(2)O2 formation. These operando and in situ studies of the oxygen electrode interface, coupled with ex situ characterization, illustrate that the composition of discharge products and their proximity to the catalytic surface are important factors in the reversibility of Li-O2 cells.&lt;/p&gt;
</style></abstract><accession-num><style face="normal" font="default" size="100%">25318060</style></accession-num><notes><style face="normal" font="default" size="100%">Gittleson, Forrest S&lt;br/&gt;Ryu, Won-Hee&lt;br/&gt;Taylor, Andre D&lt;br/&gt;eng&lt;br/&gt;Research Support, Non-U.S. Gov't&lt;br/&gt;Research Support, U.S. Gov't, Non-P.H.S.&lt;br/&gt;2014/10/16 06:00&lt;br/&gt;ACS Appl Mater Interfaces. 2014 Nov 12;6(21):19017-25. doi: 10.1021/am504900k. Epub 2014 Oct 31.</style></notes><auth-address><style face="normal" font="default" size="100%">Department of Chemical and Environmental Engineering, Yale University , 9 Hillhouse Avenue, New Haven, Connecticut, United States.</style></auth-address></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Li, X.</style></author><author><style face="normal" font="default" size="100%">Huang, J. S.</style></author><author><style face="normal" font="default" size="100%">Nejati, S.</style></author><author><style face="normal" font="default" size="100%">McMillon, L.</style></author><author><style face="normal" font="default" size="100%">Huang, S.</style></author><author><style face="normal" font="default" size="100%">Osuji, C. O.</style></author><author><style face="normal" font="default" size="100%">Hazari, N.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Role of HF in oxygen removal from carbon nanotubes: implications for high performance carbon electronics</style></title><secondary-title><style face="normal" font="default" size="100%">Nano LettNano Lett</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">carbon electronics</style></keyword><keyword><style  face="normal" font="default" size="100%">carbon nanotubes</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydrofluoric acid</style></keyword><keyword><style  face="normal" font="default" size="100%">photovoltaic devices</style></keyword><keyword><style  face="normal" font="default" size="100%">silver nanowires</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Nov 12</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">11</style></number><volume><style face="normal" font="default" size="100%">14</style></volume><pages><style face="normal" font="default" size="100%">6179-84</style></pages><isbn><style face="normal" font="default" size="100%">1530-6992 (Electronic)&lt;br/&gt;1530-6984 (Linking)</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Oxygen removal from SWNTs is crucial for many carbon electronic devices. This work shows that HF treatment followed by current stimulation is a very effective method for oxygen removal. Using a procedure involving HF treatment, current stimulation and spin-casting AgNWs onto a SWNT thin film, record high efficiency SWNT/p-Si solar cells have been developed.&lt;/p&gt;
</style></abstract><accession-num><style face="normal" font="default" size="100%">25286024</style></accession-num><notes><style face="normal" font="default" size="100%">Li, Xiaokai&lt;br/&gt;Huang, Jing-Shun&lt;br/&gt;Nejati, Siamak&lt;br/&gt;McMillon, Lyndsey&lt;br/&gt;Huang, Su&lt;br/&gt;Osuji, Chinedum O&lt;br/&gt;Hazari, Nilay&lt;br/&gt;Taylor, Andre D&lt;br/&gt;eng&lt;br/&gt;Research Support, Non-U.S. Gov't&lt;br/&gt;Research Support, U.S. Gov't, Non-P.H.S.&lt;br/&gt;2014/10/07 06:00&lt;br/&gt;Nano Lett. 2014 Nov 12;14(11):6179-84. doi: 10.1021/nl502401c. Epub 2014 Oct 29.</style></notes><auth-address><style face="normal" font="default" size="100%">Department of Chemical and Environmental Engineering, Yale University , New Haven, Connecticut 06511, United States.</style></auth-address></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Gilbertson, Leanne M.</style></author><author><style face="normal" font="default" size="100%">Goodwin, David G.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author><author><style face="normal" font="default" size="100%">Pfefferle, Lisa</style></author><author><style face="normal" font="default" size="100%">Zimmerman, Julie B.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Toward Tailored Functional Design of Multi-Walled Carbon Nanotubes (MWNTs): Electrochemical and Antimicrobial Activity Enhancement via Oxidation and Selective Reduction</style></title><secondary-title><style face="normal" font="default" size="100%">Environmental Science &amp; Technology</style></secondary-title><short-title><style face="normal" font="default" size="100%">Environ. Sci. Technol.</style></short-title></titles><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Aug-05-2015</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">http://pubs.acs.org/doi/abs/10.1021/es500468y</style></url></web-urls></urls><volume><style face="normal" font="default" size="100%">48</style></volume><pages><style face="normal" font="default" size="100%">5938 - 5945</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><issue><style face="normal" font="default" size="100%">10</style></issue></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Sekol, R. C.</style></author><author><style face="normal" font="default" size="100%">Kumar, G.</style></author><author><style face="normal" font="default" size="100%">Carmo, M.</style></author><author><style face="normal" font="default" size="100%">Gittleson, F.</style></author><author><style face="normal" font="default" size="100%">Hardesty-Dyck, N.</style></author><author><style face="normal" font="default" size="100%">Mukherjee, S.</style></author><author><style face="normal" font="default" size="100%">Schroers, J.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Bulk metallic glass micro fuel cell</style></title><secondary-title><style face="normal" font="default" size="100%">SmallSmall</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Jun 24</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">12</style></number><volume><style face="normal" font="default" size="100%">9</style></volume><pages><style face="normal" font="default" size="100%">2081-5, 2026</style></pages><isbn><style face="normal" font="default" size="100%">1613-6829 (Electronic)&lt;br/&gt;1613-6810 (Linking)</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><accession-num><style face="normal" font="default" size="100%">23184888</style></accession-num><notes><style face="normal" font="default" size="100%">Sekol, Ryan C&lt;br/&gt;Kumar, Golden&lt;br/&gt;Carmo, Marcelo&lt;br/&gt;Gittleson, Forrest&lt;br/&gt;Hardesty-Dyck, Nathan&lt;br/&gt;Mukherjee, Sundeep&lt;br/&gt;Schroers, Jan&lt;br/&gt;Taylor, Andre D&lt;br/&gt;eng&lt;br/&gt;Research Support, U.S. Gov't, Non-P.H.S.&lt;br/&gt;Germany&lt;br/&gt;2012/11/28 06:00&lt;br/&gt;Small. 2013 Jun 24;9(12):2081-5, 2026. doi: 10.1002/smll.201201647. Epub 2012 Nov 26.</style></notes><auth-address><style face="normal" font="default" size="100%">Chemical and Environmental Engineering Department, Yale University, 9 Hillhouse Ave, New Haven, CT 06511, USA.</style></auth-address></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Pasquini, L. M.</style></author><author><style face="normal" font="default" size="100%">Sekol, R. C.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author><author><style face="normal" font="default" size="100%">Pfefferle, L. D.</style></author><author><style face="normal" font="default" size="100%">Zimmerman, J. B.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Realizing comparable oxidative and cytotoxic potential of single- and multiwalled carbon nanotubes through annealing</style></title><secondary-title><style face="normal" font="default" size="100%">Environ Sci TechnolEnviron Sci Technol</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">*Hot Temperature</style></keyword><keyword><style  face="normal" font="default" size="100%">Cell Survival/*drug effects</style></keyword><keyword><style  face="normal" font="default" size="100%">Electrochemical Techniques</style></keyword><keyword><style  face="normal" font="default" size="100%">Glutathione/metabolism</style></keyword><keyword><style  face="normal" font="default" size="100%">Nanotubes, Carbon/*toxicity</style></keyword><keyword><style  face="normal" font="default" size="100%">Oxidation-Reduction</style></keyword><keyword><style  face="normal" font="default" size="100%">Photoelectron Spectroscopy</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Aug 6</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">15</style></number><volume><style face="normal" font="default" size="100%">47</style></volume><pages><style face="normal" font="default" size="100%">8775-83</style></pages><isbn><style face="normal" font="default" size="100%">1520-5851 (Electronic)&lt;br/&gt;0013-936X (Linking)</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The potential applications as well as the environmental and human health implications of carbon nanomaterials are well represented in the literature. There has been a recent focus on how specific physicochemical properties influence carbon nanotube (CNT) function as well as cytotoxicity. The ultimate goal is a better understanding of the causal relationship between fundamental physiochemical properties and cytotoxic mechanism in order to both advance functional design and to minimize unintended consequences of CNTs. This study provides characterization data on a series of multiwalled carbon nanotubes (MWNTs) that underwent acid treatment followed by annealing at increasing temperatures, ranging from 400 to 900 degrees C. These results show that MWNTs can be imparted with the same toxicity as single-walled carbon nanotubes (SWNTs) by acid treatment and annealing. Further, we were able to correlate this toxicity to the chemical reactivity of the MWNT suggesting that it is a chemical rather than physical hazard. This informs the design of MWNT to be less hazardous or enables their implementation in antimicrobial applications. Given the reduced cost and ready dispersivity of MWNTs as compared to SWNTs, there is a significant opportunity to pursue the use of MWNTs in novel applications previously thought reserved for SWNTs.&lt;/p&gt;
</style></abstract><accession-num><style face="normal" font="default" size="100%">23802737</style></accession-num><notes><style face="normal" font="default" size="100%">Pasquini, Leanne M&lt;br/&gt;Sekol, Ryan C&lt;br/&gt;Taylor, Andre D&lt;br/&gt;Pfefferle, Lisa D&lt;br/&gt;Zimmerman, Julie B&lt;br/&gt;eng&lt;br/&gt;Comparative Study&lt;br/&gt;Research Support, Non-U.S. Gov't&lt;br/&gt;2013/06/28 06:00&lt;br/&gt;Environ Sci Technol. 2013 Aug 6;47(15):8775-83. doi: 10.1021/es401786s. Epub 2013 Jul 26.</style></notes><auth-address><style face="normal" font="default" size="100%">Department of Chemical and Environmental Engineering, Yale University, New Haven, Connecticut 06520-8286, United States.</style></auth-address></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Jung, Y.</style></author><author><style face="normal" font="default" size="100%">Li, X.</style></author><author><style face="normal" font="default" size="100%">Rajan, N. K.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author><author><style face="normal" font="default" size="100%">Reed, M. A.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Record high efficiency single-walled carbon nanotube/silicon p-n junction solar cells</style></title><secondary-title><style face="normal" font="default" size="100%">Nano LettNano Lett</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Jan 9</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">1</style></number><volume><style face="normal" font="default" size="100%">13</style></volume><pages><style face="normal" font="default" size="100%">95-9</style></pages><isbn><style face="normal" font="default" size="100%">1530-6992 (Electronic)&lt;br/&gt;1530-6984 (Linking)</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Carrier transport characteristics in high-efficiency single-walled carbon nanotubes (SWNTs)/silicon (Si) hybrid solar cells are presented. The solar cells were fabricated by depositing intrinsic p-type SWNT thin-films on n-type Si wafers without involving any high-temperature process for p-n junction formation. The optimized cells showed a device ideality factor close to unity and a record-high power-conversion-efficiency of &amp;gt;11%. By investigating the dark forward current density characteristics with varying temperature, we have identified that the temperature-dependent current rectification originates from the thermally activated band-to-band transition of carriers in Si, and the role of the SWNT thin films is to establish a built-in potential for carrier separation/collection. We have also established that the dominant carrier transport mechanism is diffusion, with minimal interface recombination. This is further supported by the observation of a long minority carrier lifetime of ~34 mus, determined by the transient recovery method. This study suggests that these hybrid solar cells operate in the same manner as single crystalline p-n homojunction Si solar cells.&lt;/p&gt;
</style></abstract><accession-num><style face="normal" font="default" size="100%">23237412</style></accession-num><notes><style face="normal" font="default" size="100%">Jung, Yeonwoong&lt;br/&gt;Li, Xiaokai&lt;br/&gt;Rajan, Nitin K&lt;br/&gt;Taylor, Andre D&lt;br/&gt;Reed, Mark A&lt;br/&gt;eng&lt;br/&gt;2012/12/15 06:00&lt;br/&gt;Nano Lett. 2013 Jan 9;13(1):95-9. doi: 10.1021/nl3035652. Epub 2012 Dec 17.</style></notes><auth-address><style face="normal" font="default" size="100%">Department of Electrical Engineering, Yale University, New Haven, Connecticut 06520, USA. yeonwoong.jung@yale.edu</style></auth-address></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Zhang, S.</style></author><author><style face="normal" font="default" size="100%">Pelligra, C. I.</style></author><author><style face="normal" font="default" size="100%">Keskar, G.</style></author><author><style face="normal" font="default" size="100%">Jiang, J.</style></author><author><style face="normal" font="default" size="100%">Majewski, P. W.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author><author><style face="normal" font="default" size="100%">Ismail-Beigi, S.</style></author><author><style face="normal" font="default" size="100%">Pfefferle, L. D.</style></author><author><style face="normal" font="default" size="100%">Osuji, C. O.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Directed self-assembly of hybrid oxide/polymer core/shell nanowires with transport optimized morphology for photovoltaics</style></title><secondary-title><style face="normal" font="default" size="100%">Adv Mater</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Liquid Crystals/chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">Nanowires/*chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">Oxides/*chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">Polymers/*chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">Zinc Oxide/chemistry</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2012</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Jan 3</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">1</style></number><volume><style face="normal" font="default" size="100%">24</style></volume><pages><style face="normal" font="default" size="100%">82-7</style></pages><isbn><style face="normal" font="default" size="100%">1521-4095 (Electronic)&lt;br/&gt;0935-9648 (Linking)</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><accession-num><style face="normal" font="default" size="100%">22113991</style></accession-num><notes><style face="normal" font="default" size="100%">Zhang, Shanju&lt;br/&gt;Pelligra, Candice I&lt;br/&gt;Keskar, Gayatri&lt;br/&gt;Jiang, Jie&lt;br/&gt;Majewski, Pawel W&lt;br/&gt;Taylor, Andre D&lt;br/&gt;Ismail-Beigi, Sohrab&lt;br/&gt;Pfefferle, Lisa D&lt;br/&gt;Osuji, Chinedum O&lt;br/&gt;eng&lt;br/&gt;Research Support, U.S. Gov't, Non-P.H.S.&lt;br/&gt;Germany&lt;br/&gt;2011/11/25 06:00&lt;br/&gt;Adv Mater. 2012 Jan 3;24(1):82-7. doi: 10.1002/adma.201103708. Epub 2011 Nov 23.</style></notes><auth-address><style face="normal" font="default" size="100%">Department of Chemical and Environmental Engineering, Yale University, 9 Hillhouse Ave., New Haven, CT 06511, USA.</style></auth-address></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Gittleson, F. S.</style></author><author><style face="normal" font="default" size="100%">Kohn, D. J.</style></author><author><style face="normal" font="default" size="100%">Li, X.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Improving the assembly speed, quality, and tunability of thin conductive multilayers</style></title><secondary-title><style face="normal" font="default" size="100%">ACS NanoACS Nano</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2012</style></year><pub-dates><date><style  face="normal" font="default" size="100%">May 22</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">5</style></number><volume><style face="normal" font="default" size="100%">6</style></volume><pages><style face="normal" font="default" size="100%">3703-11</style></pages><isbn><style face="normal" font="default" size="100%">1936-086X (Electronic)&lt;br/&gt;1936-0851 (Linking)</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">While inhomogeneous thin conductive films have been sought after for their flexibility, transparency, and strength, poor control in the processing of these materials has restricted their application. The versatile layer-by-layer assembly technique allows greater control over film deposition, but even this has been hampered by the traditional dip-coating method. Here, we employ a fully automated spin-spray layer-by-layer system (SSLbL) to rapidly produce high-quality, tunable multilayer films. With bilayer deposition cycle times as low as 13 s (~50% of previously reported) and thorough characterization of film conductance in the near percolation region, we show that SSLbL permits nanolevel control over film growth and efficient formation of a conducting network not available with other methods of multilayer deposition. The multitude of variables from spray time, to spin rate, to active drying available with SSLbL makes films generated by this technique inherently more tunable and expands the opportunity for optimization and application of composite multilayers. A comparison of several polymer-CNT systems deposited by both spin-spray and dip-coating exemplifies the potential of SSLbL assembly to allow for rapid screening of multilayer films. Ultrathin polymer-CNT multilayers assembled by SSLbL were also evaluated as lithium-ion battery electrodes, emphasizing the practical application of this technique.</style></abstract><accession-num><style face="normal" font="default" size="100%">22515634</style></accession-num><notes><style face="normal" font="default" size="100%">Gittleson, Forrest S&lt;br/&gt;Kohn, David J&lt;br/&gt;Li, Xiaokai&lt;br/&gt;Taylor, Andre D&lt;br/&gt;eng&lt;br/&gt;2012/04/21 06:00&lt;br/&gt;ACS Nano. 2012 May 22;6(5):3703-11. doi: 10.1021/nn204384f. Epub 2012 May 7.</style></notes><auth-address><style face="normal" font="default" size="100%">Department of Chemical Engineering, Yale University, P.O. Box 208286, New Haven, Connecticut 06520-8286, USA.</style></auth-address></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Li, X.</style></author><author><style face="normal" font="default" size="100%">Gittleson, F.</style></author><author><style face="normal" font="default" size="100%">Carmo, M.</style></author><author><style face="normal" font="default" size="100%">Sekol, R. C.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Scalable fabrication of multifunctional freestanding carbon nanotube/polymer composite thin films for energy conversion</style></title><secondary-title><style face="normal" font="default" size="100%">ACS NanoACS Nano</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2012</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Feb 28</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">2</style></number><volume><style face="normal" font="default" size="100%">6</style></volume><pages><style face="normal" font="default" size="100%">1347-56</style></pages><isbn><style face="normal" font="default" size="100%">1936-086X (Electronic)&lt;br/&gt;1936-0851 (Linking)</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Translating the unique properties of individual single-walled carbon nanotubes (SWNTs) to the macroscale while simultaneously incorporating additional functionalities into composites has been stymied by inadequate assembly methods. Here we describe a technique for developing multifunctional SWNT/polymer composite thin films that provides a fundamental engineering basis to bridge the gap between their nano- and macroscale properties. Selected polymers are infiltrated into a Mayer rod coated conductive SWNT network to fabricate solar cell transparent conductive electrodes (TCEs), fuel cell membrane electrode assemblies (MEAs), and lithium ion battery electrodes. Our TCEs have an outstanding optoelectronic figure of merit sigma(dc)/sigma(ac) of 19.4 and roughness of 3.8 nm yet are also mechanically robust enough to withstand delamination, a step toward scratch resistance necessary for flexible electronics. Our MEAs show platinum utilization as high as 1550 mW/mg(Pt), demonstrating our technique's ability to integrate ionic conductivity of the polymer with electrical conductivity of the SWNTs at the Pt surface. Our battery anodes, which show reversible capacity of approximately 850 mAh/g after 15 cycles, demonstrate the integration of electrode and separator to simplify device architecture and decrease overall weight. Each of these applications demonstrates our technique's ability to maintain the conductivity of SWNT networks and their dispersion within a polymer matrix while concurrently optimizing key complementary properties of the composite. Here, we lay the foundation for the assembly of nanotubes and nanostructured components (rods, wires, particles, etc.) into macroscopic multifunctional materials using a low-cost and scalable solution-based processing technique.</style></abstract><accession-num><style face="normal" font="default" size="100%">22236330</style></accession-num><notes><style face="normal" font="default" size="100%">Li, Xiaokai&lt;br/&gt;Gittleson, Forrest&lt;br/&gt;Carmo, Marcelo&lt;br/&gt;Sekol, Ryan C&lt;br/&gt;Taylor, Andre D&lt;br/&gt;eng&lt;br/&gt;Research Support, Non-U.S. Gov't&lt;br/&gt;Research Support, U.S. Gov't, Non-P.H.S.&lt;br/&gt;2012/01/13 06:00&lt;br/&gt;ACS Nano. 2012 Feb 28;6(2):1347-56. doi: 10.1021/nn2041544. Epub 2012 Jan 24.</style></notes><auth-address><style face="normal" font="default" size="100%">Chemical &amp; Environmental Engineering Department, Yale University, New Haven, Connecticut 06511, United States.</style></auth-address></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Carmo, M.</style></author><author><style face="normal" font="default" size="100%">Sekol, R. C.</style></author><author><style face="normal" font="default" size="100%">Ding, S.</style></author><author><style face="normal" font="default" size="100%">Kumar, G.</style></author><author><style face="normal" font="default" size="100%">Schroers, J.</style></author><author><style face="normal" font="default" size="100%">Taylor, A. D.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Bulk metallic glass nanowire architecture for electrochemical applications</style></title><secondary-title><style face="normal" font="default" size="100%">ACS NanoACS Nano</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2011</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Apr 26</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">4</style></number><volume><style face="normal" font="default" size="100%">5</style></volume><pages><style face="normal" font="default" size="100%">2979-83</style></pages><isbn><style face="normal" font="default" size="100%">1936-086X (Electronic)&lt;br/&gt;1936-0851 (Linking)</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Electrochemical devices have the potential to pose powerful solutions in addressing rising energy demands and counteracting environmental problems. However, currently, these devices suffer from meager performance due to poor efficiency and durability of the catalysts. These suboptimal characteristics have hampered widespread commercialization. Here we report on Pt(57.5)Cu(14.7)Ni(5.3)P(22.5) bulk metallic glass (Pt-BMG) nanowires, whose novel architecture and outstanding durability circumvent the performance problems of electrochemical devices. We fabricate Pt-BMG nanowires using a facile and scalable nanoimprinting approach to create dealloyed high surface area nanowire catalysts with high conductivity and activity for methanol and ethanol oxidation. After 1000 cycles, these nanowires maintain 96% of their performance-2.4 times as much as conventional Pt/C catalysts. Their properties make them ideal candidates for widespread commercial use such as for energy conversion/storage and sensors.</style></abstract><accession-num><style face="normal" font="default" size="100%">21370891</style></accession-num><notes><style face="normal" font="default" size="100%">Carmo, Marcelo&lt;br/&gt;Sekol, Ryan C&lt;br/&gt;Ding, Shiyan&lt;br/&gt;Kumar, Golden&lt;br/&gt;Schroers, Jan&lt;br/&gt;Taylor, Andre D&lt;br/&gt;eng&lt;br/&gt;2011/03/05 06:00&lt;br/&gt;ACS Nano. 2011 Apr 26;5(4):2979-83. doi: 10.1021/nn200033c. Epub 2011 Mar 3.</style></notes><auth-address><style face="normal" font="default" size="100%">Chemical &amp; Environmental Engineering Department, Yale University, New Haven, Connecticut 06511, USA.</style></auth-address></record></records></xml>